I was walking out the door when I saw it.
Black dress shirt, ironed, ready for a dinner reservation I had made three weeks ago. And right across the left side, a white chalky streak from my antiperspirant that had transferred when I pulled the shirt over my head. Twelve minutes until I needed to leave.
Most people in that moment throw the shirt in the wash and grab something else. I didn’t have something else. So I stood in my bathroom researching frantically, found a method that took ninety seconds, and walked out the door looking completely normal.
  Here’s what most guides about how to get deodorant off black clothes get wrong: they treat every deodorant mark as the same problem. It isn’t. A fresh white streak you just made pulling your shirt on is a completely different situation from the crusty gray buildup in your armpits that’s been accumulating for months.
The fix for one takes ninety seconds and no products. The fix for the other takes an hour and a different set of tools entirely.

Quick Answer: How to Get Deodorant Off Black Clothes
For a fresh white mark made today: don’t add water. Rub the stained area firmly with a piece of nylon fabric (a pair of tights, a nylon sock, or even the inside of a nylon bag) in small circular motions. The texture lifts the dry aluminum salt residue off the fabric surface without damaging the dye. Takes sixty to ninety seconds. For set-in buildup that’s been through multiple washes: soak the affected area in undiluted white vinegar for 30 to 60 minutes, scrub gently with an old toothbrush, and launder in cold water. Never use chlorine bleach on black clothes, and use hydrogen peroxide with extreme caution as it can strip dark fabric dye.

Two Different Problems That Need Two Different Solutions
Understanding why deodorant marks look the way they do on black clothes changes everything about how you treat them.
The white streaks you see when you’ve just pulled on a shirt are dry aluminum salt residue. Most antiperspirants use aluminum chlorohydrate or aluminum zirconium compounds to physically block sweat ducts and reduce moisture. These aluminum salts are white solids suspended in a liquid or wax base. When the deodorant hasn’t fully dried before you dress, those white solids transfer directly from your skin to the fabric. They sit on the surface of the fibers, not bonded to them. That’s why the fresh-mark fixes work so well and so quickly. You’re removing a surface deposit, not breaking a chemical bond.
The gray or white crusty buildup you see in the armpit area of shirts you’ve worn many times is a different problem entirely. That’s accumulated aluminum salt that has mixed with sweat proteins, dried repeatedly, and over multiple wash and dry cycles has begun to bond with the fabric fibers themselves. Regular laundry detergent can’t touch it because the chemical bond requires acid to break. The buildup also stiffens the fabric, which is why old armpit areas on black shirts often 

Author